A Fiat and Mercedes collided by the Monktonhead Roundabout on Wednesday at 6.25pm.
The Troon pair were rushed to hospital suffering from back and neck pain after their Fiat overturned.
When firefighters arrived at the scene they had managed to get out of the vehicle.
They were kept overnight in hospital for assessment.
An elderly woman was checked for shock at the scene.
A 73-year-old man from Germany has been charged with dangerous driving after the incident.
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